OFF/ON switching of circularly polarized luminescence by oxophilic interaction of homochiral sulfoxide-containing o-OPEs with metal cations
Articolo
Data di Pubblicazione:
2018
Abstract:
Here we describe a new class of CPL switches based on oxophilic interactions between chiral sulfoxide-containing ortho-phenylene ethynylene (o-OPE) foldamers and cationic metals. These systems
represent a unique case combining high glum values (up to 0.7x10-2) and high quantum yields in both folded ON and unfolded OFF CPL states.
represent a unique case combining high glum values (up to 0.7x10-2) and high quantum yields in both folded ON and unfolded OFF CPL states.
Tipologia CRIS:
1.1 Articolo in rivista
Keywords:
Catalysis; Electronic, Optical and Magnetic Materials; Ceramics and Composites; Chemistry (all); Surfaces, Coatings and Films; 2506; Materials Chemistry2506 Metals and Alloys
Elenco autori:
Reiné, Pablo; Ortuño, Ana M.; Resa, Sandra; Álvarez de Cienfuegos, Luis; Blanco, Victor; Ruedas-Rama, M. José; Mazzeo, Giuseppe; Abbate, Sergio; Lucotti, Andrea; Tommasini, Matteo; Guisán-Ceinos, Santiago; Ribagorda, Maria; Campaña, Araceli G.; Mota, Antonio; Longhi, Giovanna; Miguel, Delia; Cuerva, Juan M.
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