Publication Date:
2021
Abstract:
The Deep Eutectic Solvents/Systems (DESs) choline chloride:urea (xChCl = 0.33) and choline chloride:glycolic acid (xChCl = 0.5) were investigated using viscosity-corrected 35Cl NMR spectroscopy and molecular dynamics simulations to probe the role of chloride as a function of water content. Three Cl- solvation regimes are revealed, with high-symmetry environments for pure and highly dilute DES, and an unusual low-symmetry interstitial region where the primary coordination sphere is most disordered. This journal is
CRIS type:
1.1 Articolo in rivista
List of contributors:
Di Pietro, M. E.; Hammond, O.; Van Den Bruinhorst, A.; Mannu, A.; Padua, A.; Mele, A.; Costa Gomes, M.
Published in: