Isotropic-nematic phase transition in liquid crystals

The paper derives the evolution equations for a nematic liquid crystal, under the action of an electromagnetic field, and characterizes the transition between the isotropic and the nematic state. The non-simple character of the continuum is described by means of the director, of the degree of orientation and their space and time derivatives. Both the degree of orientation and the director are regarded as internal variables and their evolution is established by requiring compatibility with the second law of thermodynamics. As a result, admissible forms of the evolution equations are found in terms of appropriate terms arising from a free-enthalpy potential. For definiteness a
free-enthalpy is then considered which provides directly the dielectric and magnetic anisotropies. A characterization is given of thermally-induced transitions with the degree of orientation as a phase parameter.