CLOSED VERSUS OPEN CYCLE ENERGY RECOVERY FROM SOLID OXIDE FUEL CELLS

Acomputermodelofasolidoxidefuelcell(SOFC)wasimplementedwithanumberof operational options to evaluate the best use of the cell waste heat. The simplest solution for heat recovery is represented by adopting a pressurized fuel cell with the eventual expansion of the exhaust stream in a gas turbine. Other alternatives feature the adoption of various closed cycle recovery systems: a standard steam cycle, an inter-refrigerated helium cycle, and an advanced binary cycle. Assuming a fuel energy input of 100 MW, the overall efficiency of a hybrid cell was computed, which was much higher than that of a small capacity (100 kW ) existing plant (67 versus ∼53 per cent). Such high efficiency hybrid SOFC systems were taken as the reference to evaluate the performance of alternate options. Reclaiming the cell waste heat by means of a subcritical steam cycle yields a performance similar to that of a hybrid system. Similar results are obtained resorting to a closed helium cycle. Advanced binary cycles, using either potassium or cesium as working fluids, were extensively investigated in view of achieving a superior overall performance. The hot, clean stream exhausted by the fuel cell is recognized as an ideal heat source for a binary plant. The SOFC-binary cycle system was fully optimized yielding top efficiencies ∼74 per cent and an additional power output of ∼45 per cent of the cell rating (30 per cent in the case of the hybrid system). The excellent efficiency of a binary cycle combined with the large amount of oxygen that is available in the cell exhaust flow suggests that a supplementary firing of the fuel could improve the overall merit of the system. Burning 75 per cent of the additional natural gas, for example, reduces the total efficiency to a level of that of a hybrid system but makes available an extra power 1.35 times greater than the fuel cell capacity. Pushing further this concept, the fuel cell could become an auxiliary equipment of a binary cycle.